Don’t do any of that on Libre. Make sure to turn all these chrome settings off - not automatic but off.
If you’re unable to find any blocked or allowed content in your hostlog made shown chrome at all chrome is rerouting the data effectively bypassing blokada.
Blokada dns is not supposed to block any content at all.
It’s important that your android blokada app isn’t bypassed by Google chrome. That’s what they do with “asynchronous dns” or “async dns” or “data saver” and similar features all of which have been discussed here already:
I’d ask you to look through your chrome flags and settings for these features and turn them all off if you want to continue to use chrome. If that’s done and your browser cache is cleared we’ll have a look again.